Leighton Meester - MTV VMAs 2009

Leighton Meester poses for some pictures as she arrives at the 2009 MTV Video Music Awards at the Radio City Music Hall in New York City on Sunday (September 13).

The 23-year-old Gossip Girl actress was wearing a sequin petal sleeve shift dress by Christian Cota, Giuseppe Zanotti shoes, a Bottega Veneta clutch, and jewelry by Cathy Waterman.

At the event, Twilight‘s Ashley Greene looked at Leighton and said, “You look incredible. I thought you were going to be on the best-dressed list, and I’m sure that you are.”

Leighton also presented an award together with comedian Jack Black.

10+ pictures inside of Leighton Meester at the 2009 MTV VMAs…