Leighton Meester Hits Up CMA Awards 2010

Leighton Meester rocks an Emilio Pucci dress at the 2010 CMA Awards on Wednesday (November 10) held at the Bridgestone Arena in Nashville, Tennessee.

The 24-year-old Gossip Girl star paired it with Jimmy Choo‘s “Ciara” platform sandal and Cathy Waterman jewels.

Earlier this week, Leighton stepped out in Marc Jacobs for the premiere of her latest film Country Strong.

She also got glammed up while shooting a commercial for the next Vera Wang fragrance, which she’s the new face of!