Leighton Meester - MTV Movie Awards 2011 Red Carpet

Leighton Meester sparkles on the red carpet at the 2011 MTV Movie Awards held at Universal Studios’ Gibson Amphitheatre on Sunday (June 5) in Universal City, Calif.

The 25-year-old Gossip Girl actress wore a Balmain dress from the Fall/Winter 2011 collection, Pierre Hardy shoes, Paco Rabane bag, and Bulgari jewels.

Unfortunately, The Roommate‘s Leighton didn’t win Best Villian, losing out to Tom Felton for his work in Harry Potter and the Deathly Hallows: Part 1.

The 2011 MTV Movie Awards broadcast LIVE from Sunday, June 5 @ 9pm ET/8pm CT. Saturday Night Live regular Jason Sudeikis is hosting the ceremony!