Keira Knightley & James Righton: Valentino Ball in Venice!

Keira Knightley and her husband James Righton step out together at an event for the first time as a married couple at the Valentino Ball held during the 2013 Venice Film Festival on Wednesday (September 4) at Palazzo Volpi in Venice, Italy.

The 28-year-old actress and James, 30, were seen the next day heading through the airport to catch a flight out of town.

PHOTOS: Check out the latest pics of Keira Knightley

Keira and James got married back in May in a very intimate ceremony.

10+ pictures inside of Keira Knightley and James Righton at the 2013 Venice Film Festival…