The 46-year-old actor was joined by actor Jeff Daniels and his wife Kathleen Treado on the red carpet.
At the show, Liev is acting as a presenter while Jeff is nominated for Outstanding Lead Actor in a Drama Series for his work in The Newsroom.
Make sure to tune in for the 2014 Emmy Awards, hosted by Seth Meyers, airing right now on NBC!
FYI: Jeff is wearing head to toe Prada. Liev is wearing Calvin Klein Collection.