The 52-year-old actor and Alice separated back in January, People confirmed first.
Nicolas and Alice, who are the parents of a 10-year-old son named Kal-el, got married back in August 2004 after meeting just months earlier.
In an interview from a few years ago, Nicolas said that he got married quickly so that Alice could travel with him while he worked on a movie.
“You can connect the dots,” he told The Guardian. “And we did it because we loved each other… I made a very clear decision to marry out of my own zip code. I mean, way out of my own zip code. I married into another culture, and it’s interesting because in Korea they call me the Son-in-Law.”