The 39-year-old actor and his love were joined at the event by a pregnant Busy Philipps, who showed off her big baby bump on the carpet, and his How I Met Your Mother co-star Cobie Smulders with her husband, SNL funnyman Taran Killam.
The Norma Jean gala raised money for the children of Hollygrove, which advocated for thriving families.
FYI: Cobie is wearing a Bibhu Mohapatra dress, Lana Jewelry studs and a Devi Kroell clutch.
10+ pictures inside of Neil Patrick Harris, Busy Philipps, and more at the Norma Jean gala… More Here! »